33380-11-9Relevant articles and documents
Gantar, D.,Rahten, A.,Volavshek, B.
, p. 227 - 236 (1987)
Formation of the superoctahedral heteropolyanion [Ni(TaF6)6]4- through oxidation of tantalum with ammonium fluoride at the Monel-container wall
Schoening, Robert-A,Meyer, Gerd
, p. 1759 - 1762 (2008/10/09)
A few single crystals of (NH4)4[Ni(TaF6)6] are obtained besides (NH4)[TaF6] as the main product of the reaction of (NH4)F with tantalum powder in an He-arc-welded Monel metal container at 400°C. The crystal structure (trigonal, R-3c (Nr. 167), Z = 6, a = 1723,0(2); c = 2166,6(2) pm; R1 = 0,0303, wR2 = 0,0609) contains the superoctahedral heteropolyanion [Ni(TaF6)6]4- and (NH4)+ ions; it may be recognized as a derivative structure of the K4CdCl6 type according to (NH4)4[Ni(TaF6)6]≡K 4[Cd(Cl)6].