33395-22-1

Upstream product

• 603-35-0 triphenylphosphine 

Downstream Products

• 84181-07-7 {P(C₆H₅)3}2Pd(CH₃OCH₂CCCH₂OCH₃) 
• 15227-23-3 bis-(triphenylphosphane)-sulfato-palladium(II) 
• 15227-22-2 sulfur dioxide-tris(triphenylphosphane)-palladium⁽⁰⁾ 
• 105915-74-0 sulfur dioxide-bis(triphenylphosphane)-palladium⁽⁰⁾ 
• 15629-88-6 (P(C₆H₅)3)2Pd(CH₃OOCCCCOOCH₃) 
• 75249-92-2 {μ-(Ph3P)2PdS2}Fe2(CO)6 
• 79839-96-6 {(C₆H₅C)3}Pd{P(C₆H₅)3}2⁽¹⁺⁾*ClO₄^(1-) 
• 84181-06-6 {P(C₆H₅)3}2Pd(HOCH₂CCCH₂OCH₃) 
• 84181-09-9 {P(C₆H₅)3}2Pd(HOCH₂CCCH₂OC₂H₅) 
• 104437-84-5 bis(triphenylphosphine)((2-vinylphenyl)diphenylphosphine)palladium⁽⁰⁾ 
• 175790-20-2 Pd2(μ-2-(methoxycarbonyl)allyl)(μ-Cl)(triphenylphosphine)2 
• 175790-21-3 Pd2(μ-CH2C(CN)CH2)(μ-Cl)(triphenylphosphine)2 
• 175790-25-7 Pd2(μ-2-(methoxycarbonyl)allyl)(μ-Br)(triphenylphosphine)2 
• 175790-35-9 Pd2(μ-CH2C(OCH2Ph)CH2)(μ-Cl)(triphenylphosphine)2 

Relevant academic research and scientific papers

Palladium(0)-alkene bis(triarylphosphine) complexes as catalyst precursors for the methoxycarbonylation of styrene

The fluorous complex [Pd(0)(P{C6H4-p-SiMe 2(CH2CH2C6F13)} 3)2(MA)] (MA = maleic anhydride) was synthesized and characterized by its NMR spectra. Together with the nonfluorous complexes [Pd(0)(PPh3)2(alkene)] (alkene = C2H 4) (NC)2C=C(CN)2), NCC(H)= C(H)CN, MA, or benzoquinone) these were evaluated as catalyst precursors in the methoxycarbonylation of styrene. The nonfluorous C2H4 and MA complexes gave the highest conversions (the turnover number (TON) was 120; the (average) turnover frequency (TOF) amounted to 80 h-1). The fluorous complex gave a significantly lower conversion (TON about 38; TOF 26 h-1) than its nonfluorous counterpart, which is caused by a lower stability of the fluorous complex under the reaction conditions.