333955-57-0Relevant academic research and scientific papers
Bimetallic reactivity. On the use of oxadiazoles as binucleating ligands
Incarvito,Rheingold,Qin,Gavrilova,Bosnich
, p. 1386 - 1390 (2001)
Two (1,3,4)-oxadiazole ligands have been prepared. In one case the oxadiazole ring is flanked by two o-aniline groups, and in the other case it is an extension of the first where the amines are condensed with 2-picolyl groups. A monometallic copper(II) complex of the former has been prepared, and its crystal structure was determined. A number of bimetallic copper(II), cobalt(II,), and nickel(II) complexes of the di-deprotonated latter ligand were prepared and isolated. The crystal structure of the cobalt(II) complex bearing two acetate bridges is reported. The work demonstrates that the seldom-employed oxadiazole ring can be used effectively for generating bimetallic complexes.
