33422-93-4

Basic information

• Product Name: 3,6-anhydro-7-deoxy-L-gluco-2-heptulose phenylosazone
• CAS NO: 33422-93-4
• Molecular Weight: 354.409
• Mol File: 33422-93-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3,6-anhydro-7-deoxy-L-gluco-2-heptulose phenylosazone(CAS DataBase Reference)
• NIST Chemistry Reference: 3,6-anhydro-7-deoxy-L-gluco-2-heptulose phenylosazone(33422-93-4)
• EPA Substance Registry System: 3,6-anhydro-7-deoxy-L-gluco-2-heptulose phenylosazone(33422-93-4)

Safety Data

• Hazardous Substances Data: 33422-93-4(Hazardous Substances Data)

Upstream product

• 5328-53-0 7-deoxy-L-manno-2-heptulose phenylosazone 

Downstream Products

• 82977-13-7 4-(5-deoxy-α-L-arabinofuranosyl)-2-phenyl-2H-1,2,3-triazole 
• 82977-14-8 4-(5-deoxy-β-L-arabinofuranosyl)-2-phenyl-2H-1,2,3-triazole 

Relevant articles and documents

STRUCTURE AND ANOMERIC CONFIGURATION OF THE C-NUCLEOSIDE ANALOGS OBTAINED BY DEHYDRATION OF 7-DEOXY-L-manno-2-HEPTULOSE PHENYLOSAZONE

Dehydration of 7-deoxy-L-manno-2-heptulose phenylosazone with methanolic sulfuric acid afforded two 3,6-anhydro-osazone derivatives (2 and 3).Refluxing the anhydro-osazones with copper sulfate gave two C-nucleoside analogs, namely, 4-(5-deoxy-α-L-arabinofuranosyl)-2-phenyl-$v-triazole (4) and 4-(5-deoxy-β-L-arabinofuranosyl)-2-phenyl-$v-triazole (5).The structure and anomeric configurations of 2,4, and 5 were determined by n.m.r. spectroscopy.The preponderant conformation of 4 and 5, and the mass spectra of 2,4, and 5 are discussed.