334519-09-4

Basic information

• Product Name: (6S,8S,9S,10S,11R)-9,10,11-Tris-benzyloxy-8-iodomethyl-1,7-dioxa-spiro[5.5]undec-3-ene
• CAS NO: 334519-09-4
• Molecular Weight: 612.505
• Mol File: 334519-09-4.mol

Chemical Properties

• CAS DataBase Reference: (6S,8S,9S,10S,11R)-9,10,11-Tris-benzyloxy-8-iodomethyl-1,7-dioxa-spiro[5.5]undec-3-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (6S,8S,9S,10S,11R)-9,10,11-Tris-benzyloxy-8-iodomethyl-1,7-dioxa-spiro[5.5]undec-3-ene(334519-09-4)
• EPA Substance Registry System: (6S,8S,9S,10S,11R)-9,10,11-Tris-benzyloxy-8-iodomethyl-1,7-dioxa-spiro[5.5]undec-3-ene(334519-09-4)

Safety Data

• Hazardous Substances Data: 334519-09-4(Hazardous Substances Data)

Downstream Products

• 334519-10-7 (6S,9S,10S,11R)-9,10,11-Tris-benzyloxy-8-methylene-1,7-dioxa-spiro[5.5]undec-3-ene 
• 334519-11-8 (6S,8S,9R,10S,11R)-9,10,11-Tris-benzyloxy-1-oxa-spiro[5.5]undec-3-en-8-ol 

Relevant articles and documents

Triisobutylaluminium mediated carbocyclisation of sugar derived spiroketals and ketosides

The carbocyclisation of sugar derived spiroketals and ketosides under the agency of triisobutylaluminium is presented. In addition, the synthetic usefulness of cyclooctenic product 21, derived from the corresponding exo-glycal 20, was shown by its transformation into conformationally locked L-idose analogues 22 and 23.