334645-34-0Relevant academic research and scientific papers
Synthesis of (±)-epoxysorbicillinol using a novel cyclohexa-2,5-dienone with synthetic applications to other sorbicillin derivatives
Pettus, Liping H.,Van De Water, Ryan W.,Pettus, Thomas R. R.
, p. 905 - 908 (2007/10/03)
matrix presented A novel route to epoxysorbicillinol as well as dimers of sorbicillin is reported. The synthesis is - in principle - amenable to enantioselectivity. The key step is an oxidative dearomatization to produce a stable and highly malleable p-quinol intermediate, which undergoes a highly diastereoselective epoxidation.
