334875-18-2Relevant academic research and scientific papers
Aqueous phase semihydrogenation of alkynes over Ni-Fe bimetallic catalysts
Awasthi, Mahendra K.,Barman, Sudipta Roy,Behrens, Silke,Rai, Rohit K.,Singh, Sanjay K.,Singh, Vipin K.
, p. 4968 - 4980 (2020/08/19)
Bimetallic Ni-Fe catalysts (Ni/Fe, 1?:?1, 1?:?3, and 3?:?1) are synthesized and explored for their catalytic activity in semihydrogenation of internal alkynes using H2 gas in water-ethanol solution. Our findings revealed that over the Ni1Fe3 catalyst a high diastereoselectivity for Z-alkenes with a high conversion for a wide range of internal alkynes can be achieved at moderate reaction temperature (40 °C). Notably, the selectivity for the Z-alkenes is enhanced in the presence of n-butyl amine as an additive. Deuterium labeling experiments evidenced that H2 gas becomes dissociated homolytically over the catalyst surface to hydrogenate alkynes to alkenes. Synthesized catalysts were successfully characterized by HR-TEM, SEM, XPS, EDS, P-XRD and H2-TPD.
Reactions of vinyltributylgermanes and aryl halides under Heck conditions
Torres, Nicole M.,Lavis, Jér?me M.,Maleczka Jr., Robert E.
experimental part, p. 4407 - 4410 (2009/10/26)
We describe the palladium-mediated reaction of vinyltributylgermanes with aryl halides under Heck conditions. Depending on their degree of substitution, (E)-vinyltributylgermanes preferentially afford either the cine or Z-alkenyl coupled products in moder
Highly activated vinyl hydrogen in a significantly twisted styrene
Mori, Hajime,Matsuo, Takafumi,Yoshioka, Yasunori,Katsumura, Shigeo
, p. 9004 - 9012 (2007/10/03)
(Chemical Equation Presented) The novel example of a vinylic hydrogen more reactive than a benzylic hydrogen was found by treatment of a twisted styrene derivative with a strong base followed by D2O quenching. In this paper, the full details of
Vinyl hydrogen more reactive than benzyl hydrogen toward base in significantly twisted styrenes
Mori, Hajime,Matsuo, Takafumi,Yoshioka, Yasunori,Katsumura, Shigeo
, p. 3093 - 3095 (2007/10/03)
The novel example of vinyl hydrogen more reactive than benzylic hydrogen was found by treatment of a twisted styrene derivative with a strong base followed by D2O quenching. The characteristic nature of the vinyl hydrogen, which is activated by
