33493-71-9

Usage

Chemical Properties

White to yellowish powder

InChI:InChI=1/C34H35NO6/c1-24(36)35-30-32(38)31(37)29(41-33(30)39-22-25-14-6-2-7-15-25)23-40-34(26-16-8-3-9-17-26,27-18-10-4-11-19-27)28-20-12-5-13-21-28/h2-21,29-33,37-38H,22-23H2,1H3,(H,35,36)/t29-,30-,31-,32-,33+/m1/s1

Upstream product

• 76-83-5 trityl chloride 
• 13343-62-9 benzyl 2-acetamido-2-deoxy-α-D-glucopyranoside 

Downstream Products

• 33289-63-3 benzyl 2-acetamido-3,4-di-O-acetyl-6-O-trityl-2-deoxy-α-D-glucopyranoside 
• 58006-42-1 benzyl 2-acetamido-2,3,4-trideoxy-α-D-erythro-hex-3-enopyranoside 
• 58006-45-4 benzyl 2-acetamido-2,3,4-trideoxy-6-O-trityl-α-D-erythro-hex-3-enopyranoside 
• 74024-09-2 benzyl 2-acetamido-3,4-anhydro-2-deoxy-α-D-allopyranoside 
• 74024-20-7 benzyl 2-acetamido-6-O-acetyl-2,3,4-trideoxy-α-D-erythro-hex-3-enopyranoside 
• 74024-10-5 benzyl 2-acetamido-6-O-acetyl-3,4-anhydro-2-deoxy-α-D-allopyranoside 
• 74024-14-9 benzyl 2-acetamido-2,3,4-trideoxy-6-O-trityl-α-D-glucopyranoside 
• 74024-06-9 benzyl 2-acetamido-3,4-anhydro-2-deoxy-6-O-trityl-α-D-allopyranose 
• 74024-12-7 benzyl 2-acetamido-2,4-dideoxy-4-iodo-6-O-trityl-α-D-glucopyranoside 
• 74024-17-2 benzyl 2-acetamido-3-O-acetyl-2,4-dideoxy-4-fluoro-6-O-trityl-α-D-gulopyranoside 
• 74024-21-8 N-((2S,3R,4S,5R,6R)-2-Benzyloxy-5-fluoro-4-hydroxy-6-trityloxymethyl-tetrahydro-pyran-3-yl)-acetamide 
• 83009-13-6 benzyl 2-acetamido-6-O-acetyl-2-deoxy-3,4-di-O-(4-phenylbenzyl)-α-D-glucopyranoside 
• 83009-14-7 benzyl 2-acetamido-2-deoxy-3,4-di-O-(4-phenylbenzyl)-α-D-glucopyranoside 
• 122768-12-1 γ-benzyl ester of (benzyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-α-D-glucopyranosid)uronyl-L-alanyl-D-isoglutamine 

Relevant academic research and scientific papers

The cobalt-catalyzed oxygenative radical route from hexopyranosides to carbapentofuranoses

Cobalt-catalyzed radical cyclization/oxygenation of various 6-iodohex-1-enitols gave in one step the carbocyclic analogs of pentofuranoses. The reaction was run under very mild conditions and gave moderate to good yields of carbapentofuranoses within a few hours. All the possible 6-iodohex-1-enitol stereoisomers were prepared, and the influence of relative configurations and protecting groups was studied.

SYNTHESIS OF URONOYLDIPEPTIDE DERIVATIVES OF N-ACETYLGLUCOSAMINE AND OF N-ACETYLMURAMOYLDIPEPTIDE

Starting from benzyl 3,4-di-O-acetyl-6-O-trityl-N-acetyl-β-glucosamine and benzyl α-benzyl-4-O-acetyl-N-acetylmuramate, 2-acetamido-2-deoxy-D-glucopyranuronyl-L-alanyl-D-isoglutamine and O-(2-acetamido-2-deoxy-D-glucopyranuronyl-L-alanyl-D-isoglutamin-3-y