334972-47-3

Upstream product

• 334972-54-2 (S)-tert-butyl((2-((4-methoxybenzyl)oxy)hex-5-en-1-yl)oxy)dimethylsilane 
• 334972-43-9 (S)-5-(tert-Butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)pentanal 
• 334972-53-1 (S)-1-((tert-butyldimethylsilyl)oxy)hex-5-en-2-ol 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 
• 127102-61-8 (S)-hex-5-ene-1,2-diol 
• 334972-46-2 Ethyl (R)-2-[(2'R,5'S)-5'-(4-methoxybenzyloxy)tetrahydropyran-2'-yl]-6-methylhept-5-enoate 

Downstream Products

• 334972-48-4 (1S,2S,5R)-2-[(2'R,5'S)-5'-(4-Methoxybenzyloxy)tetrahydropyran-2'-yl]-5-(1-methylethenyl)cyclopentanol 
• 334972-61-1 (1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane 
• 350485-98-2 (1S,2R,5R)-2-[(2'R,5'S)-5'-(4-Methoxybenzyloxy)tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane 

Relevant academic research and scientific papers

Synthesis of (+)-testudinariol A, a triterpene metabolite of the marine mollusc Pleurobrancus testudinarius

Testudinariol A (1) is an ichthyotoxic and structurally unusual triterpene alcohol isolated from the skin and the mucus of the marine mollusc Pleurobrancus testudinarius. A stereoselective synthesis of (+)-1 was achieved by starting from (R)-glycidol.

Triterpenoid total synthesis. Part 6. Synthesis of testudinariols A and B, triterpene metabolites of the marine mollusc Pleurobrancus testudinarius

Testudinariols A (1) and B (1′) are ichthyotoxic and structurally unusual triterpene alcohols isolated from the skin and the mucus of the marine mollusc Pleurobrancus testudinarius. The first synthesis of (+)-1 and (+)-1′ was achieved by starting from (R)-glycidol.