334979-03-2Relevant academic research and scientific papers
Transition metal (Group 6, Ru and Group 10) derivatives of aminophosphines, Ph2PN(H)R (R=Ph, C6H11)
Priya, Srinivasan,Balakrishna, Maravanji S.,Mague, Joel T.
, p. 116 - 124 (2007/10/03)
The reactions of aminophosphines with Group 6 metal carbonyls afford both mono-substituted and disubstituted complexes. The reaction of Ph2PN(H)C6H11 with molybdenum tetracarbonyl derivative gives a mixture of cis and trans-isomers. The reaction of Ph2PN(H)Ph with Pd(COD)Cl2 leads to the P-N bond cleavage to give chloro bridged dimer, [Pd(PPh2O)(PPh2OH) (μ-Cl)]2, whereas with Pt(COD)Cl2, disubstituted cis-[PtCl2{PPh2N (H)R}2]2 was obtained. The reaction of Ph2PN(H)C6H11 with RuCl2(DMSO)4 or RuCl2(PPh3)3 leads to the formation of ionic complex, [RuCl{Ph2PN(H)C6 H11}3]Cl.
Molybdenum tetracarbonyl complexes with functionalised aminophosphine ligands: cis-[Mo(CO)4(PPh2NHR)2] (R = Ph, But) - Molecular structures of PMes2NHPh (Mes = 2,4,6-Me3C6H2
Kühl, Olaf,Blaurock, Steffen,Sieler, Joachim,Hey-Hawkins, Evamarie
, p. 111 - 117 (2008/10/08)
The aminophosphines PPh2NHR [R = Ph (1a), But (1b)] react readily with cis-[Mo(CO)4(NCEt)2] to give cis-[Mo(CO)4(PPh2NHR)2] [R = Ph (2), But (3)] in high yield, while
