335022-67-8

Upstream product

• 653-37-2 perfluorobenzaldehyde 
• 24850-33-7 allyltributylstanane 
• 85116-38-7 (+)-diisopinocampheylallylborane 
• 107-37-9 allyltrichlorosilane 

Downstream Products

• 765941-46-6 Acrylic acid (R)-1-pentafluorophenyl-but-3-enyl ester 
• 765941-80-8 (3S,4S,6R)-3,4-dihydroxy-6-pentafluorophenyltetrahydropyran-2-one 
• 765941-64-8 (6R)-6-pentafluorophenyl-5,6-dihydropyran-2-one 
• 694503-83-8 (R)-1-Pentafluorophenyl-butane-1,4-diol 

Relevant academic research and scientific papers

Titanium catalysed enantioselective addition of allyltributyltin to aldehydes: A simple and easily reproducible procedure

We describe here an extremely simple procedure for the enantioselective addition of allyltributyltin to aldehydes in the presence of a binaphthol-titanium complex. In toluene or pentane, the reaction can be performed at room temperature in the absence of

Structurally simple pyridine N-oxides as efficient organocatalysts for the enantioselective allylation of aromatic aldehydes

A series of structurally simple pyridine N-oxides have readily been assembled from inexpensive amino acids and tested as organocatalysts in the allylation of aldehydes with allyl(trichloro)silane to afford homoallylic alcohols. (S)-Proline-based catalysts

Diastereoselective dihydroxylation and regioselective deoxygenation of dihydropyranones: A novel protocol for the stereoselective synthesis of C 1-C8 and C15-C21 subunits of (+)-discodermolide

Diastereoselective dihydroxylation of dihydropyranones and subsequent regioselective α-deoxygenation provides 1,3-trans-β-hydroxy-6- lactones stereoselectively. This protocol has been applied for the synthesis of C1-C8 and C15-C21 subunits of (+)-discodermolide.