335645-72-2Relevant academic research and scientific papers
A new method for synthesizing a pyrrole ring and its application to the development of new π-systems
Takeda, Mineko,Matsumoto, Shoji,Ogura, Katsuyuki
, p. 231 - 236 (2007/10/03)
A new type of reaction was developed for the construction of a pyrrole ring. When 1,8-disubstituted 2,7-bis(p-tolylsulfonyl)-l,7-octadiene-3,6-diynes (6) was treated with an aniline derivative (7) in the presence of CuCl (1.6 equiv.) and CuCl2 (0.16 equiv.) in DMF (at 90 °C), one 2-sulfony-1-alken-3-yne part of 6 was converted to a 1-arylpyrrole skeleton in a reasonable yield.
