33603-14-4

Basic information

• Product Name: (E)-2-chloro-1-phenylethenyl methyl ether
• CAS NO: 33603-14-4
• Molecular Weight: 168.623
• Mol File: 33603-14-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-2-chloro-1-phenylethenyl methyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-chloro-1-phenylethenyl methyl ether(33603-14-4)
• EPA Substance Registry System: (E)-2-chloro-1-phenylethenyl methyl ether(33603-14-4)

Safety Data

• Hazardous Substances Data: 33603-14-4(Hazardous Substances Data)

Upstream product

• 27904-70-7 1-methoxy-1-phenyl-2,2,2-trichloroethane 

Relevant articles and documents

1,2-H shift in copper-chlorocarbenoid intermediate during CuCl/bpy-promoted stereoselective dechlorination of 2,2,2-trichloroethyl alkyl ethers to (Z)-1-alkoxy-2-chloroethenes

(Chemical Equation Presented) Reaction of 2,2,2-trichloroethyl alkyl ethers with 2 molar equiv of CuCl/bpy in refluxing DCE yielded (Z)-1-alkoxy-2- chloroethenes stereoselectively as the major product via 1,2-H shift in copper-chlorocarbenoid intermediate. 2,2,2-Trichloroethyl carboxylates undergo a radical 1,2-acyloxy shift under similar conditions.