336181-38-5Relevant academic research and scientific papers
TO WHAT EXTENT IS A ?-ALLYLIC INTERMEDIATE INVOLVED IN SOME PALLADIUM-CATALYZED ALKYLATIONS ?
Fiaud, J. C.,Malleron, J. L.
, p. 1399 - 1402 (1981)
Comparison of polarimetric data in the asymmetric palladium-catalyzed addition of sodium dimethyl malonate on optically active and racemic 2-cyclohexenyl and carveyl acetates suggests that the reaction does not got- at least totally -through a symmetric ?-allylic cationic intermediate.
