336193-49-8Relevant articles and documents
Synthesis of (Z)-vinylsilanes with high diastereoselectivity by using samarium diiodide
Concelloen, Jose M.,Bernad, Pablo L.,Bardales, Eva
, p. 937 - 939 (2007/10/03)
matrix presented β-Elimination of O-acetyl 1-chloro-1-trimethylsilylalkan-2-ols 1 was achieved by using samarium diiodide as a metaling reagent and afforded the corresponding (Z)-vinylsilanes with high stereoselectivity. The starting compounds 1 were easi