33664-95-8

Basic information

• Product Name: 4-(tert-butyl)-5,5-dimethyloxazolidin-2-one
• Synonyms: 4-(tert-butyl)-5,5-dimethyloxazolidin-2-one
• CAS NO: 33664-95-8
• Molecular Weight: 171.239
• Mol File: 33664-95-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-(tert-butyl)-5,5-dimethyloxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(tert-butyl)-5,5-dimethyloxazolidin-2-one(33664-95-8)
• EPA Substance Registry System: 4-(tert-butyl)-5,5-dimethyloxazolidin-2-one(33664-95-8)

Safety Data

• Hazardous Substances Data: 33664-95-8(Hazardous Substances Data)

Upstream product

• 690-37-9 2,4,4-trimethyl-2-pentanol 

Relevant articles and documents

Controllable Intramolecular Unactivated C(sp3)-H Amination and Oxygenation of Carbamates

Dual catalyst-controlled intramolecular unactivated C(sp3)-H amination and oxygenation of carbamates merging visible-light photocatalysis and earth-abundant transition metal catalysis have been reported. Useful amino alcohol and diol derivatives could be selectively obtained from readily available tertiary alcohol derivatives. The possible mechanisms have been proposed via a 1,5-HAT process followed by Lewis acid-controlled cyclization. The nickel and zinc catalysts inhibit the formation of oxygenation and amination products, respectively. An interesting phenomenon of chirality transfer is also observed.