33673-34-6

Usage

InChI:InChI=1/C10H14ClNO/c11-10(12-13)8-2-6-1-7(4-8)5-9(10)3-6/h6-9H,1-5H2

Upstream product

• 4500-12-3 2-adamantanone oxime 
• 700-58-3 2-Adamantanone 
• 54564-31-7 2-nitroadamantane 

Downstream Products

• 69788-00-7 C₂₀H₂₃NO 
• 70951-51-8 α,α-Adamantyliden-N-(2-phenyl)-prop-1-en-3-yl-nitron 
• 700-58-3 2-Adamantanone 
• 4500-12-3 2-adamantanone oxime 
• 57777-70-5 α,α-adamantylidene-N-methyl nitrone 
• 76300-15-7 adamantan-2-one O-methyloxime 
• 106577-14-4 adamantalydene ethyl nitron 
• 65094-34-0 α,α-adamantylidene-N-phenyl nitrone 
• 76300-14-6 α,α-adamantylidene-N-benzyl nitrone 
• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 76300-20-4 adamantanone oxime O-benzyl ether 

Relevant academic research and scientific papers

New and improved methods for the conversion of nitroalkanes into geminal chloronitroso compounds

The scope and limitations of a new method for the preparation of geminal chloronitroso compounds involving treatment of a nitronate anion with oxalyl chloride are described in full, and a milder, high yielding, and more chemoselective variant using the de

Chlorination of oximes with aqueous H2O2/HCl system: Facile synthesis of gem-chloronitroso- and gem-chloronitroalkanes, gem-chloronitroso- and gem-chloronitrocycloalkanes

Chlorination of cyclic and linear ketone oximes with aqueous H 2O2/HCl in a two-phase dichloromethane-water system selectively affords gem-chloronitroso compounds in yields of up to 94%. One-pot oxidation of the resulting gem-chloronitroso compounds with peracetic acid, prepared in situ, gives gem-chloronitroalkanes and cycloalkanes in yields of up to 82%. The advantages of the method are that it is facile and environmentally benign and does not require gaseous chlorine. Georg Thieme Verlag Stuttgart.