33715-08-1Relevant academic research and scientific papers
Neighboring group participation of phosphine oxide functionality in the highly regio- and stereoselective iodohydroxylation of 1,2-allenylic diphenyl phosphine oxides
Guo, Hao,Qian, Rong,Guo, Yinlong,Ma, Shengming
, p. 7934 - 7938 (2008/12/22)
(Chemical Equation Presented) Two sets of reaction conditions were established to enable the highly regio- and stereoselective iodohydroxylation of 1,2-allenylic diphenyl phosphine oxides, yielding (E)-2-iodo-3-hydroxy-1- alkenyl diphenyl phosphine oxides
Carbanion-Accelerated Claisen Rearrangements. 7. Phosphine Oxide and Phosphonate Anion Stabilizing Groups
Denmark, Scott E.,Marlin, John E.
, p. 1003 - 1013 (2007/10/02)
The utility of phosphine oxide and phosphonate groups has been examined in the context of the carbanion-accelerated Claisen rearrangement (CACR).Both of the groups permit the construction of substituted allyl vinyl ethers by allyl oxide addition to phosph
