33733-50-5Relevant academic research and scientific papers
Palladium-Catalyzed Germylation of Aryl Bromides and Aryl Triflates Using Hexamethyldigermane
Komami, Narumi,Matsuoka, Keitaro,Yoshino, Tatsuhiko,Matsunaga, Shigeki
, p. 2067 - 2075 (2018)
Palladium-catalyzed germylation of aryl bromides and aryl triflates using commercially available hexamethyldigermane is described. Optimized reaction conditions afforded various functionalized aryltrimethylgermanes, including drug-like molecules, in moderate to good yields, demonstrating the versatility of the presented protocols.
Mechanism and Selectivity of Aryltrimethylgermane Cation Radical Fragmentations
Feinberg, Elizabeth C.,Dinnocenzo, Joseph P.
, p. 8639 - 8644 (2020/07/03)
Aryltrimethylgermane cation radicals were generated by nanosecond transient absorption spectroscopy. Transient kinetics experiments show that the aryltrimethylgermane cation radicals react with added nucleophiles in reactions that are first-order in both
