3374-16-1Relevant academic research and scientific papers
Perfluoromethyl element ligands. XLI. [1] compounds of the type (F3C)2EE′R with pseudohalide character (E = P, As; E′ = S, Se, Te)
Grobe,Vetter
, p. 2085 - 2094 (2008/10/08)
Perfluoromethyl phosphorus and -arsenic compounds of the type (F3C)2EE′R (E = P, As; E′ = S, Se, Te; R = organic group) are prepared either by dismutation (metathesis) of E2(CF3)4 with (RE′)2/su
Synthesis of Thiol, Selenol, and Tellurol Esters by the Reaction of Organochalcogeno Mercurials with Acid Chlorides
Silveira, Claudio C.,Braga, Antonio L.,Larghi, Enrique L.
, p. 5183 - 5186 (2008/10/08)
Summary: Thiol, selenol, and tellurol esters were prepared by the reaction of bis(organochalcogeno)mercurials with acid chlorides in chloroform or carbon tetrachloride and in the presence of tetrabutylammonium halides as catalysts.
Syntheses and Vibrational Spectra of Some Tris(alkanethiolato)mercurate(II) Complexes, and Crystal Structure of the Hexakis-(methanethiolato)dimercurate(II) Dianion
Bowmaker, Graham A.,Dance, Ian G.,Dobson, Brian C.,Rogers, David Alan
, p. 1607 - 1618 (2007/10/02)
The complexes (R = Me, cation = Et4N+; R = But, cation = Et4N+, Bu4N+, +) have been prepared.The crystal structure of the methanethiolate complex shows that it contains centrosymmetric dinuclear anions 2- with distorted tetrahedral geometry about the mercury atoms.Vibrational spectroscopic evidence suggests that this complex dissociates on dissolution in ethanol to give mononuclear - species.The ButS- complexes appear to exist as mononuclear t)3>- species both in the solid state and in solution.The metal-sulfur stretching frequencies are assigned for all of the complexes studied, and the vibrational spectra are discussed in terms of the structures of the complex anions involved.Crystal data for 2Hg2(SCH3)6: a 8.656(5), b 9.130(6), c 12.368(8) Angstroem; α 102.16(4), β 105.51(4), γ 105.29(4) deg; space group P, Z 1, R 0.034, Rw 0.042.
