337525-54-9Relevant academic research and scientific papers
Binuclear vanadium(V) complexes of bis(aryl)adipohydrazone: Synthesis, spectroscopic studies, crystal structure and catalytic activity
Asghari Lalami, Nasim,Hosseini Monfared, Hassan,Noei, Hashem,Mayer, Peter
, p. 669 - 677 (2011)
Three new binuclear vanadium(V) complexes of bis(aryl)adipohydrazones (H4L1 = bis((2-hydroxynaphthalen-1-yl)methylene) adipohydrazide, H4L2 = bis(5-bromo-2-hydroxybenzylidene) adipohydrazide, and H4L
Homobimetallic organotin(IV) complexes with hexadentate Schiff base: Synthesis, crystal structure and antimicrobial studies
Shujah, Shaukat,Zia-Ur-Rehman,Muhammad, Niaz,Shah, Afzal,Ali, Saqib,Meetsma, Auke,Hussain, Zahid
, p. 19 - 26 (2014)
This article describes the synthesis of four new homobimetallic organotin(IV) complexes: [Et2Sn]2L (1), [Bu 2Sn]2L (2), [Oct2Sn]2L (3) and [BuClSn]2L (4) (H4L = N1′,N 6′-bis(5-bromo-2-hydroxybenzylidene)adipodihydrazide) and their structural elucidation by means of elemental analysis, mass spectroscopy, FT-IR, NMR (1H, 13C, 119Sn) and single crystal X-ray analysis. Spectroscopic studies indicate coordination of hexadentate ligand to the diorganotin(IV) moieties via ONO-ONO donor sites and pentacoordinated tin centers. Single crystal X-ray analysis of (1) and (2) revealed homobimetallic nature of complexes with each Sn atom in a distorted square pyramidal coordination geometry. Packing diagrams suggest the seminal role of Sna?N and Bra?π interactions in generating supramolecular assembly. The synthesized compounds were screened for their antimicrobial activity and cytotoxicity. Compound (2) exhibit highest activity against several pathogenic microbes.
Binuclear organotin(IV) complexes with adipic dihydrazones: Synthesis, spectral characterization, crystal structures and antibacterial activity
Sedaghat, Tahereh,Aminian, Marjan,Bruno, Giuseppe,Amiri Rudbari, Hadi
, p. 26 - 31 (2013/07/04)
New organotin(IV) complexes, (R2Sn)2L [L = L a: R = Me (1), Ph (2); L = Lb: R = Me (3), Ph (4)] have been synthesized by reaction of dihydrazone ligands, bis(5-bromosalicylaldehyde) adipicdihydrazone (H4/s
