33777-04-7Relevant articles and documents
A new one-pot synthesis of 2-quaternary 1,3-diketones
Ren,Wang,Dou,Fan,He,Song,Xia,Li,Jia,Li,Tu
, p. 2384 - 2388 (2001)
A facile one-pot synthesis of 1,3-diketones with stereogenic quaternary center at C-2 has been developed on the basis of an oxidative-rearrangement of a series of tertiary α-hydroxy epoxides on treatment with pyridinium chlorochromate (PCC). A possible mechanism is also discussed.