3378-37-8Relevant academic research and scientific papers
Direct transformation of benzilic amines to carbonyls using polyacrylamide-bound tungstate under phase-transfer catalysis conditions
Hamamoto, Hiromi,Suzuki, Yachiyo,Takahashi, Hideyo,Ikegami, Shiro
, p. 4239 - 4242 (2008/02/08)
A recyclable catalytic system under heterogeneous phase-transfer catalysis conditions was designed by using polyacrylamide-bound tungstate. A convenient method for the oxidative direct transformation of benzilic amines to carbonyls with hydrogen peroxide was then developed.
Methyltrioxorhenium-Catalyzed Oxidation of Secondary and Primary Amines with Hydrogen Peroxide
Yamazaki, Shigekazu
, p. 877 - 883 (2007/10/03)
The methyltrioxorhenium-catalyzed oxidation of secondary amines and primary amines with hydrogen peroxide has been carried out. The oxidation of secondary amines afforded nitrones in good-to-excellent yield. Benzylamines were selectively oxidized to oximes, while general primary alkylamines possessing the α-C -H bond gave mixtures of oximes, nitroso dimers, and azoxy compounds.
OXIDATION OF PRIMARY ALIPHATIC AMINES WITH SODIUM PERBORATE
Zajac, Walter W.,Darcy, Michael G.,Subong, Amador P.,Buzby, John H.
, p. 6495 - 6496 (2007/10/02)
A biphasic system of ethyl acetate and water containing sodium perborate, sodium bicarbonate and N,N,N',N'-tetraacetylethylenediamine oxidizes primary aliphatic amines to aliphatic C-nitroso compounds in good to excellent yields.
Oxidation of Primary Aliphatic Amines to C-Nitroso Dimers
Zajac, Walter W.,Walters, Thomas R.,Woods, James M.
, p. 808 - 810 (2007/10/02)
A biphasic system of ethyl acetate or dichloromethane and water containing sodium percarbonate (Na2CO3*3/2H2O2), sodium hydrogen carbonate and N,N,N',N'-tetraacetylethylenediamine oxidizes primary aliphatic amines to aliphatic C-nitroso dimers in most cases in good to excellent yields.
