337980-54-8Relevant academic research and scientific papers
Modular synthesis of triazole-containing triaryl α-helix mimetics
Ehlers, Ina,Maity, Prantik,Aube, Jeffrey,Koenig, Burkhard
scheme or table, p. 2474 - 2490 (2011/06/10)
We describe novel scaffold designs for nonpeptidic α-helix mimetics. The tricyclic scaffolds contain triazoles and reproduce amino acid side chains i, i+3, and i+7. The three different scaffolds are synthetically readily accessible, allow the introduction
Improved and new syntheses of potential molecular electronics devices
Price Jr., David W.,Dirk, Shawn M.,Maya, Francisco,Tour, James M.
, p. 2497 - 2518 (2007/10/03)
New syntheses of ethyl and nitro substituted oligo(phenylene ethynylene)s (OPEs) have been developed. To further explore whether the presence of nitro functionality in OPEs leads to switching and memory capabilities, new nitro substituted OPEs have been designed and synthesized. An isatogen-based system, a structure that is isomeric to the nitro OPE, has been synthesized. Additionally, pyridine-based and chromium-based compounds have been synthesized. We surmise that redox reactions of these candidates may impart switching capabilities and electrochemical studies are shown. U-shaped OPEs were synthesized to inhibit leakage of metals deposited during formation of top contacts on self-assembled monolayers (SAMs). The OPEs contain either thiol-based moieties or isonitrile groups to enable formation of SAMs on metal substrates.
Benzyltriethylammonium dichloroiodate/sodium bicarbonate combination as an inexpensive, environmentally friendly, and mild iodinating reagent for anilines
Kosynkin, Dmitry V.,Tour, James M.
, p. 991 - 992 (2007/10/03)
(matrix presented) Monoiodinated anilines were prepared in good to excellent yields by the action of benzyltriethylammonium dichloroioadate on anilines in the presence of sodium bicarbonate and methanol. The iodinating reagent was prepared in an environmentally friendly fashion without the use of organic solvents.
