33834-54-7Relevant academic research and scientific papers
A general and efficient method to convert selenides into selenones by using HOF·CH3CN
Potash, Shay,Rozen, Shlomo
, p. 5574 - 5579 (2013/09/12)
A general route for the preparation of selenones (R2SeO 2) is presented. This task is achieved through the quick and high-yielding reaction of selenides (R2Se) with HOF·CH 3CN. The reaction tolerates some elusiv
Aqueous sodium hypochlorite mediated chemoselective oxidation of chalcogenides to monoxides and dioxides by microwave exposure
Khurana, Jitender,Nand, Bhaskara
experimental part, p. 906 - 909 (2011/01/08)
A solvent-free, rapid, and highly selective oxidation of sulfides, selenides, and tellurides (chalcogenides) to the corresponding monoxides (sulfoxides, selenoxides, and telluroxides) or the corresponding dioxides (sulfones, selenones, and tellurones) has been developed using aqueous sodium hypochlorite on solid supports by exposure to microwave. Chemoselectivity and quantitative yields have been attained in most cases.
Efficient trapping of the intermediates in the photooxygenation of sulfides by aryl selenides and selenoxides
Sofikiti, Nikoletta,Rabalakos, Constantinos,Stratakis, Manolis
, p. 1335 - 1337 (2007/10/03)
Aryl selenides and selenoxides trap efficiently the intermediates in the reaction of singlet oxygen with sulfides. In the co-photooxygenation of 1equiv of an aryl selenoxide with 1.3equiv of dimethyl sulfide, the aryl selenone is formed quantitatively. Ar
Rapid oxidation of selenides, selenoxides, tellurides, and telluroxides with aqueous sodium hypochlorite
Khurana, Jitender M.,Kandpal, Bhaskar M.,Chauhan, Yogendra K.
, p. 1369 - 1375 (2007/10/03)
A simple and convenient procedure for the rapid oxidation of a variety of selenides, selenoxides, tellurides, and telluroxides with aqueous sodium hypochlorite to selenones and tellurones, respectively, has been reported in dimethylformamide at ambient te
