33847-65-3Relevant academic research and scientific papers
An anionic zerovalent nickel carbonyl complex supported by a triphosphine borate ligand: An Ni-C≡O-Li isocarbonyl
Hou, Hongyi,Rheingold, Arnold L.,Kubiak, Clifford P.
, p. 231 - 233 (2005)
An anionic zerovalent nickel carbonyl complex, [Ni(PhBP3)(CO)] [Li(TMED)] (1), supported by a triphosphine borate ligand was prepared and structurally characterized. The solid state structure shows the coordination of Li+ to the O atom of the CO ligand. The isocarbonyl structure indicates strong electron donor ability of the [PhBP3] ligand and charge redistribution to the carbonyl oxygen. Results of a DFT calculation support this view. Complex 1 represents the first example of a Lewis acid O atom adduct of a Ni(0) carbonyl complex.
Polytertiary phosphines and arsines. III. Metal complexes of the tritertiary phosphine bis(2-diphenylphosphinoethyl)phenylphosphine
King,Kapoor, Pramesh N.,Kapoor, Ramesh N.
, p. 1841 - 1850 (2008/10/08)
Metal complexes of the tritertiary phosphine [(C6H5)2PCH2CH2] 2PC6H5 (Pf-Pf-Pf) are discussed. This tritertiary phosphine can bond to transition metals in all six poss
