338741-85-8Relevant academic research and scientific papers
(Thiolan-2-yl)diphenylmethyl benzyl ether/N,N′-diarylurea cocatalyzed asymmetric aziridination of cinnamyl bromide and aryl aldimine
Wang, Shang-Hua,Chein, Rong-Jie
supporting information, p. 2607 - 2615 (2016/05/11)
A dual catalyst system using THT-based chiral sulfide 2a and H-bond donor 10a was developed for the asymmetric imino Corey-Chaykovsky reaction. Under the optimum reaction conditions, cinnamyl bromide reacted with a wide scope of N-diphenylphosphinic aldim
Enantioselective synthesis of diaryl aziridines using tetrahydrothiophene- based chiral sulfides as organocatalysts
Huang, Meng-Ting,Wu, Hsin-Yi,Chein, Rong-Jie
supporting information, p. 1101 - 1103 (2014/01/17)
This work describes catalytic and asymmetric aziridinations (15 examples, 95-98% ee) of benzyl bromide and imines via the imino Corey-Chaykovsky reaction using (thiolan-2-yl)diarylmethanol benzyl ether as an organocatalyst. The catalyst and analogues thereof were prepared through an expeditious and efficient synthetic route featuring a double nucleophilic substitution and Shi epoxidation as key steps.
Enantioselective borodeuteride reduction of aldimines catalyzed by cobalt complexes: Preparation of optically active deuterated primary amines
Miyazaki, Daichi,Nomura, Kohei,Yamashita, Tatsuya,Iwakura, Izumi,Ikeno, Taketo,Yamada, Tohru
, p. 3555 - 3558 (2007/10/03)
[Equation presented] The enantioselective borodeuteride reduction catalyzed by optically active β-ketoiminato cobalt complexes was applied to N-(di(o-tolyl)phosphinyl)-aldimines to afford the corresponding optically active deuterated primary amines in hig
