338777-79-0Relevant academic research and scientific papers
N-Tosyl-1,5,2,6-dithiadiazocane: A waste-free electrophilic sulfur reagent for the efficient synthesis of medium-ring S,N-heterocycles
Javorskis, Tomas,Bagd?iunas, Gintautas,Orentas, Edvinas
, p. 4325 - 4328 (2016/03/22)
We report on the application of an eight-membered C2-symmetric sulfenamide derivative as a new convenient and highly reactive electrophilic sulfur-nucleophilic nitrogen synthon for the concise synthesis of medium-ring S,N-heterocyclic systems.
Efficient access to 1,4-benzothiazine: Palladium-catalyzed double C-S bond formation using Na2S2O3 as sulfurating reagent
Qiao, Zongjun,Liu, Hui,Xiao, Xiao,Fu, Yana,Wei, Jianpeng,Li, Yuxue,Jiang, Xuefeng
supporting information, p. 2594 - 2597 (2013/07/19)
A novel Pd-catalyzed double C-S bond formation coupling reaction has been developed. This protocol, in which Na2S2O3 was used as sulfurating reagent in metal-catalyzed reactions, provides an efficient method for the synthe
Nickel-mediated inter- and intramolecular C-S coupling of thiols and thioacetates with aryl iodides at room temperature
Xu, Xiao-Bo,Liu, Jian,Zhang, Jian-Jian,Wang, Ya-Wen,Peng, Yu
, p. 550 - 553 (2013/04/11)
A Ni(0)-catalyzed intermolecular cross-coupling of various functionalized thiols and aryl iodides has been developed and successfully extended to less explored intramolecular versions, where thioacetates could also be utilized as the strategic surrogate. Air-stable precatalysts, very mild conditions, and an easy protocol allow rapid access to medicinally useful aryl thioethers, as demonstrated in the facile synthesis of (±)-chuangxinmycin as a key step.
