33931-37-2Relevant academic research and scientific papers
FORMATION OF BENZOTHIA CROWNS IN REACTION OF THE DIALLYL DERIVATIVE OF 2-MERCAPTO-4-METHYLPHENOL WITH SCl2
Anisimov, A. V.,Grishkyan, A. A.,Gaisina, Kh. A.,Viktorova, E. A.
, p. 1084 - 1086 (1992)
The reaction of SCl2 with 1-allyloxy-2-allylthio-4-methylbenzene gave a mixture of 2,9,11,18-tetrachloromethyldi(4-methylbenzo)-1,7,10,13-tetrathia-18-crown-6- and 2,9,11,18-tetrachloromethyldi-(4-methylbenzo)-1,7,10,15-tetrathia-18-crown-6.
Synthesis of phenoxathiins and phenothiazines by aryne reactions with thiosulfonates
Hosoya, Takamitsu,Kanemoto, Kazuya,Sakata, Yuki,Yoshida, Suguru
supporting information, p. 593 - 596 (2020/05/19)
Novel synthetic methods for phenoxathiins and phenothiazines by aryne reactions are disclosed. We found that phenoxathiins were efficiently prepared by the reaction between aryne intermediates and S-(2-hydroxyaryl) 4-toluenethiosulfo-nates. A synthetic method for phenothiazines was also developed by the reaction of arynes with S-(2-aminoaryl) 4-toluenethiosulfonates.
