33933-72-1Relevant academic research and scientific papers
Secondary Phosphine Oxides as Multitalented Preligands En Route to the Chemoselective Palladium-Catalyzed Oxidation of Alcohols
Vasseur, Alexandre,Membrat, Romain,Gatineau, David,Tenaglia, Alphonse,Nuel, Didier,Giordano, Laurent
, p. 728 - 732 (2017/03/13)
Secondary phosphine oxides O=PHR2 (SPOs) were identified as multitalented preligands for the chemoselective Pd-catalyzed oxidation of alcohols by a hydrogen-abstracting methodology. SPOs were found to promote the hydrogen-abstraction step as well as hydrogen transfer to a Michael acceptor by generating a putative active H?Pd species. The catalytic system operates under neutral conditions and was proven to be compatible with various electrophilic and nucleophilic functionalities within the substrates as well as water- and air-sensitive functional groups.
The Diepoxides of Terpinolene
Carman, Raymond M.,Rayner, Anthony C.
, p. 195 - 202 (2007/10/02)
The structures of the racemic 1,2:4,8-diepoxy-p-menthanes, the diepoxides of terpinolene, are revised.The major isomer has the trans relationship between the two epoxides.
COMPOUNDS OF THE PYRAN SERIES AS COMPONENTS OF THE ESSENTIAL OILS OF Tanacetum boreale AND Ajania fastigiata
Dembitskii, A. D.,Krotova, G. I.,Suleeva, R.,Yurina, R. A.
, p. 310 - 312 (2007/10/02)
It has been established that the essential oils of Tanacetum boreale and Ajania fastigiata contain as their main components 3-hydroxy-2,2,6-trimethyl-6-vinyltetrahydropyran and its acylated and oxidized derivatives.
Novel Rearrangement of 1,2:4,8-Diepoxy-p-menthane
Ho, Tse-Lok,Stark, Charles J.
, p. 1446 - 1447 (2007/10/02)
Erhitzen von 1,2:4,8-Diepoxy-p-menthan (1) mit Aluminiumoxid in Toluol induziert eine Fragmentierung zum 6-Ethenyl-5,6-dihydro-2,2,6-trimethyl-2H-pyran-3(4H)-on (2).
