33933-72-1Relevant articles and documents
Secondary Phosphine Oxides as Multitalented Preligands En Route to the Chemoselective Palladium-Catalyzed Oxidation of Alcohols
Vasseur, Alexandre,Membrat, Romain,Gatineau, David,Tenaglia, Alphonse,Nuel, Didier,Giordano, Laurent
, p. 728 - 732 (2017/03/13)
Secondary phosphine oxides O=PHR2 (SPOs) were identified as multitalented preligands for the chemoselective Pd-catalyzed oxidation of alcohols by a hydrogen-abstracting methodology. SPOs were found to promote the hydrogen-abstraction step as well as hydrogen transfer to a Michael acceptor by generating a putative active H?Pd species. The catalytic system operates under neutral conditions and was proven to be compatible with various electrophilic and nucleophilic functionalities within the substrates as well as water- and air-sensitive functional groups.
COMPOUNDS OF THE PYRAN SERIES AS COMPONENTS OF THE ESSENTIAL OILS OF Tanacetum boreale AND Ajania fastigiata
Dembitskii, A. D.,Krotova, G. I.,Suleeva, R.,Yurina, R. A.
, p. 310 - 312 (2007/10/02)
It has been established that the essential oils of Tanacetum boreale and Ajania fastigiata contain as their main components 3-hydroxy-2,2,6-trimethyl-6-vinyltetrahydropyran and its acylated and oxidized derivatives.