33951-13-2

Basic information

• Product Name: 2-chloroethyl thioisobutyrate
• Synonyms: 2-chloroethyl thioisobutyrate
• CAS NO: 33951-13-2
• Molecular Weight: 166.672
• Mol File: 33951-13-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-chloroethyl thioisobutyrate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-chloroethyl thioisobutyrate(33951-13-2)
• EPA Substance Registry System: 2-chloroethyl thioisobutyrate(33951-13-2)

Safety Data

• Hazardous Substances Data: 33951-13-2(Hazardous Substances Data)

Upstream product

• 17643-70-8 2-isopropyl-1,3-oxathiolane 

Relevant articles and documents

KINETICS AND MECHANISM OF HOMOLYTIC TRANSFORMATIONS OF 1,3-OXATHIOLANES IN CARBON TETRACHLORIDE

In carbon tetrachloride in the presence of tert-butyl peroxide at 120-150 deg C 1,3-oxathiolanes are converted into chloroethyl thioacylates.The kinetics were studied and an unbranched radical-chain mechanism for the formation of the chlorothio esters through the formation of 2-chloro-1,3-oxathiolanes is proposed.The controlling stage of the process is the abstraction of a hydrogen atom from the substrate by the trichloromethyl radical.The effect of the nature of the heteroatom and substituent at position 2 of the heterocycle on the reactivity of the substrate was dtermined.