339570-65-9Relevant academic research and scientific papers
Preparation of sterically protected 3,4-bis[(2,4,6-tri-t-butylphenyl)phosphinidene]-1,2-bis[4-(4-vinylphenyl)butyl]c yclobutene and its polymers
Yamada, Naoki,Toyota, Kozo,Yoshifuji, Masaaki
, p. 248 - 249 (2007/10/03)
Two new sterically protected 3,4-diphosphinidenecyclo-butenes, i.e., 1,2-bis[4-(4-methylphenyl)butyl]-3,4-bis[(2,4,6-tri-t-butylphenyl)phosphinidene] cyclobutene, and 3,4-bis[(2,4,6-tri-t-butylphenyl)phosphinidene]-1,2-bis[4-(4-vinylphenyl)butyl]c yclobutene, were prepared. Copolymerization of the latter with styrene was studied. Treatment of [6-(4-vinylphenyl)hex-1-ynyl](2,4,6-tri-t-butylphenyl)phosphine with butyllithium and 1,2-dibromoethane afforded a polymer of the latter cyclobutene.
