339588-95-3

Basic information

• Product Name: Co(NC₅H₄CH₃)2(OC(O)CH(C₆H₅)2)2
• CAS NO: 339588-95-3
• Molecular Weight: 667.73
• Mol File: 339588-95-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Co(NC₅H₄CH₃)2(OC(O)CH(C₆H₅)2)2(CAS DataBase Reference)
• NIST Chemistry Reference: Co(NC₅H₄CH₃)2(OC(O)CH(C₆H₅)2)2(339588-95-3)
• EPA Substance Registry System: Co(NC₅H₄CH₃)2(OC(O)CH(C₆H₅)2)2(339588-95-3)

Safety Data

• Hazardous Substances Data: 339588-95-3(Hazardous Substances Data)

Upstream product

• 108-89-4 picoline 
• 71-48-7 cobalt(II) acetate 
• 1716-11-6 diphenylacetic acid sodium salt 

Relevant articles and documents

Investigation of Geometrical and Conformational Isomers of Cobalt(II) Bis(diphenylacetato)-bis(γ-picolinate) by Dynamic NMR Spectroscopy and Molecular Mechanics

Cobalt(II) bis(diphenylacetato)-bis(γ-picolinate) is synthesized and its geometrical and conformational isomers are investigated using dynamic NMR and molecular mechanics methods. The complex in the solution is shown to exist as cis and trans isomers, which are detected at 263 K in the course of a slow intermolecular ligand exchange. At T -O2C-CH(Ph)2 and -O2CCH(Ph)-Ph bonds slows, which results in the formation of different conformers. The energies of the retarded intermolecular exchange and of the retarded rotation of the phenyl radicals were calculated from 1H NMR and molecular mechanics data.