33965-54-7Relevant academic research and scientific papers
Regioselective SN2 opening of vinylic epoxides with trialkylzincates and trialkylaluminates
Equey, Olivier,Vrancken, Emmanuel,Alexakis, Alexandre
, p. 2151 - 2159 (2004)
The use of trialkylorganozincates and tetraalkylaluminates allows regioselective SN2 nucleophilic opening of vinylic epoxides. The reaction occurs with an anti-substitution pattern and can be applied to a wide range of substrates. We also show that the solvent and the structure of the epoxide have an influence on the substitution products' ratio. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.
Palladium-Catalyzed isomerization of exo-methylenic allylic alcohols
Fordred, Paul S.,Niyadurupola, D.Gangani,Wisedale, Richard,Bull, Stevend
scheme or table, p. 2310 - 2314 (2009/12/27)
Treatment of allylic alcohols containing a 1,1-disubstituted alkene with a palladium catalyst and hydrogen gas (1 bar) results in facile isomerization to their corresponding trisubstituted (E)-allylic alcohols, along with small amounts of the corresponding hydrogenated products.
