33983-39-0

Basic information

• Product Name: MEDICARPIN(P)
• Synonyms: MEDICARPIN(P);(6aS,11aS)-Medicarpin
• CAS NO: 33983-39-0
• Molecular Formula: C₁₆H₁₄O₄
• Molecular Weight: 270.27996
• Mol File: 33983-39-0.mol
• Article Data: 4

Chemical Properties

• Melting Point: 127-128℃
• Boiling Point: 418.8°C at 760 mmHg
• Flash Point: 207.1°C
• Appearance: /
• Density: 1.319±0.06 g/cm3 (20 ºC 760 Torr)
• Vapor Pressure: 1.31E-07mmHg at 25°C
• Refractive Index: 1.629
• CAS DataBase Reference: MEDICARPIN(P)(CAS DataBase Reference)
• NIST Chemistry Reference: MEDICARPIN(P)(33983-39-0)
• EPA Substance Registry System: MEDICARPIN(P)(33983-39-0)

Safety Data

• Hazardous Substances Data: 33983-39-0(Hazardous Substances Data)

Usage

General Description

Medicarpin(P) is a chemical compound that belongs to the group of pterocarpans, which are natural compounds found in certain plants. It is primarily found in the Medicago species of plants, such as alfalfa and clover. Medicarpin(P) has been studied for its potential pharmaceutical and agricultural applications, including its antimicrobial, antifungal, and anti-inflammatory properties. It has also been researched for its potential role in enhancing plant resistance to diseases and pests. Overall, medicarpin(P) is a bioactive compound with various potential uses in medicine and agriculture due to its unique chemical properties.

InChI:InChI=1/C16H14O4/c1-18-10-3-5-11-13-8-19-14-6-9(17)2-4-12(14)16(13)20-15(11)7-10/h2-7,13,16-17H,8H2,1H3/t13-,16-/m1/s1

Upstream product

• 1891-01-6 3-(2,4-dimethoxyphenyl)-7-hydroxy-4H-chromen-4-one 
• 1890-99-9 7-hydroxy-3-(2-hydroxy-4-methoxyphenyl)-4H-chromen-4-one 
• 108-46-3 recorcinol 
• 32383-76-9 9-methoxy-6a,11a-dihydro-6H-benzo[4,5]furo[3,2-c]chromen-3-ol 
• 6496-89-5 2,4-dimethoxyphenylacetic acid 
• 52085-14-0 4-benzoxy-salicylaldehyde 

Downstream Products

• 95541-54-1 3-{2-Hydroxy-5-[(3S,4R)-7-hydroxy-3-(2-hydroxy-4-methoxy-phenyl)-chroman-4-yl]-4-methoxy-phenyl}-2H-chromen-7-ol 
• 20879-02-1 (3S)-2'-hydroxy-4',7-dimethoxyisoflavan 
• 56866-29-6 (3S)-7-hydroxy-2',4'-dimethoxyisoflavan 
• 95541-68-7 (3S)-2'-benzyloxy-7-hydroxy-4'-methoxyisoflavan 
• 85915-64-6 (3S,4S)-3,4-trans-4-<(3S)-6',7-dihydroxy-4'-methoxyisoflavan-3'-yl>-2',7-dihydroxy-4'-methoxyisoflavan 
• 95541-51-8 (S)-3-{2-Hydroxy-5-[(3R,4S)-3-(2-hydroxy-4-methoxy-phenyl)-7-methoxy-chroman-4-yl]-4-methoxy-phenyl}-chroman-7-ol 
• 116718-23-1 (3S)-2'-hydroxy-4'-methoxy-7-methoxymethoxyisoflavan 
• 32383-76-9 medicarpin 
• 116718-34-4 5-benzyloxy-2-<2-(2-benzyloxy-4-methoxyphenyl)acetyl>-phenyl-(3S)-6',7-dibenzyloxy-4'-methoxyisoflavan-3'-carboxylate 
• 116718-30-0 3-(4-benzyloxy-2-hydroxyphenyl)-2-(2-benzyloxy-4-methoxyphenyl)-1-<(3S)-6',7-dibenzyloxy-4'-methoxyisoflavan-3'-yl>-propane-1,3-dione 
• 116718-31-1 2',7-dibenzyloxy-2-<(3S)-6',7-dibenzyloxy-4'-methoxyisoflavan-3'-yl>-4'-methoxyisoflavone 
• 116743-76-1 2',7-dihydroxy-2-<(3S)-6',7-dihydroxy-4'-methoxyisoflavan-3'-yl>-4'-methoxyisoflavone 
• 116718-27-5 methyl (3S)-2',7-di-O-benzylvestitol-5'-carboxylate 
• 116718-29-7 4-Benzyloxy-5-((S)-7-benzyloxy-chroman-3-yl)-2-methoxy-benzoyl chloride 

Relevant articles and documents

A general asymmetric route to enantio-enriched isoflavanes via an organocatalytic annulation of o-quinone methides and aldehydes

Reported herein is a general approach to optically active isoflavanes based on a chiral amine-catalyzed [4 + 2] asymmetric annulation of o-quinone methides and aldehydes. A number of naturally occurring isoflavanes, including equol, sativan, isosativan, v

Total Synthesis of (+)-Medicarpin

(+)-Medicarpin has been synthesized asymmetrically for the first time in a linear scalable process with an overall yield of 11%. The two chiral centers were constructed in one step via condensation using a chiral oxazolidinone auxiliary. This method will likely accelerate research on medicarpin as an erythropoietin inducer for erythropoietin-deficient diseases.