33985-28-3

Upstream product

• 2053-00-1 2,6-dideoxy-D-xylo-hexose 
• 108-24-7 acetic anhydride 
• 77068-14-5 methyl 2,3,6-trideoxy-4-O-(3,4-di-O-acetyl-2,6-dideoxy-α-L-lyxo-hexopyranosyl)-3-(trifluoroacetamido)-β-L-lyxo-hexopyranoside 
• 155154-09-9 (2R,3S,4S)-hept-6-ene-2,3,4-triol 

Downstream Products

• 75412-38-3 benzyl 4-O-(3,4-di-O-acetyl-2,6-didesoxy-α-L-lyxo-hexopyranosyl)-3-azido-2,3,6-tridesoxy-α-D-erythro-hex-5-enopyranoside 
• 75412-29-2 Acetic acid (2S,3R,4S,6S)-3-acetoxy-6-((2S,3S,4S,6S)-4-acetylamino-6-benzyloxy-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-4-yl ester 

Relevant academic research and scientific papers

Indium-Mediated Allylation of Aldehydes: A Convenient Route to 2-Deoxy and 2,6-Dideoxy Carbohydrates

The allylation of protected polyhydroxy aldehydes 1 and 14 has been achieved by indium metal with ultrasound promotion generating the diastereomeric pair of homoallylic polyols 3, 4 and 16, 17 respectively with moderate to good stereoselectivity.Pursuing this allylation strategy with the corresponding deprotected polyhydroxy aldehydes led to the same pair of homoallylic polyols but with a quite different ratio of the diastereomers generated.The polyols were further transformed to 2-deoxy (5 and 6) and 2,6-dideoxy (18 and 19) carbohydrates by ozonolysis.