339985-36-3Relevant academic research and scientific papers
Star-shaped Pd(II) and Pt(II) complexes containing C3-symmetric conjugated thiophenes: Synthesis, characterization, and chemical reactions with organic unsaturated molecules
Choi, Jun-Chul,Ham, Min Gyu,Kim, Yong-Joo,Park, Hee Kwon,Takeuchi, Katsuhiko
, (2022/03/19)
Triple oxidative addition reactions of [M0(styrene)(PMe3)2] (M = Pd/Pt) with C3-symmetric star-shaped molecules containing 1-, 3-, and 5-thiophene-substituted benzene, in 1:0.3 ratio, afforded new Pd(II) and Pt(II) trinuclear complexes in suitable yields. Analogous trinuclear complexes were formed by similar reactions of thiophenyl halide derivatives containing triazine or triphenylamine cores. Alternatively, a trinuclear Pd(II) complex was obtained by oxidative addition of a Pd(0) complex (synthesized from allyl(cyclopentadienyl) palladium(II), [(η5-C5H5)Pd(η3-C3H5)] with PEt3. Sonogashira-type coupling between trinuclear Pt(II) halides (containing C3-symmetric conjugated thiophenes) and alkynes, in the presence of cuprous halide and diethylamine, afforded alkynyl-containing trinuclear Pt(II) complexes with extended π-conjugation. Insertion reactions of organic isocyanides (CN-R) with trinuclear Pd(II) complexes yielded trinuclear Pd(II) imidoyl complexes by insertion of CN-R into Pd-carbon (thiophene) bonds. Reactions of trinuclear Pt(II) halides with Ag(OCOCF3) and NaN3 formed pseudohalogen-containing Pt(II) complexes.
Di(p-methoxyphenyl)amine end-capped tri(p-thiophenylphenyl)amine based molecular glasses as hole transporting materials for solid-state dye-sensitized solar cells
Bui, Thanh-Tuan,Shah, Said Karim,Sallenave, Xavier,Abbas, Mamatimin,Sini, Gjergji,Hirsch, Lionel,Goubard, Fabrice
, p. 49590 - 49597 (2015/06/16)
Three tris(thienylphenyl)amine-based molecular glass hole transporting materials were synthetized, characterized and incorporated in solid state dye-sensitized solar cells. Devices using these compounds as solid hole conductors show relatively high V
Platinum-acetylide polymers with higher dimensionality for organic solar cells
Wang, Qiwei,He, Zhicai,Wild, Andreas,Wu, Hongbin,Cao, Yong,Schubert, Ulrich S.,Chui, Chung-Hin,Wong, Wai-Yeung
, p. 1766 - 1777 (2011/12/16)
A new series of platinum(II)-acetylide polymers P1-P3 containing thiophene-triarylamine chromophores of different dimensions were synthesized and their electronic band structures, field-effect charge transport, and application in bulk heterojunction solar
New star-shaped molecules derived from thieno[3,2-b]thiophene unit and triphenylamine
Metri,Sallenave,Beouch,Plesse,Goubard,Chevrot
supporting information; experimental part, p. 6673 - 6676 (2011/02/21)
A series of new substituted triphenylamine (TPA) derivatives with alkyl thieno[3,2-b]thiophene and thiophene units were synthesized in a combinatorial manner. Suzuki coupling of a dioxaborolane TPA derivative and 2-bromo-3-nonylthieno[3,2-b]thiophene or S
Synthesis and electrochemical properties of oligo- and poly(thienylphenylamine)s
Yamamoto, Kimihisa,Higuchi, Masayoshi,Uchida, Kumiko,Kojima, Yojiro
, p. 5782 - 5788 (2007/10/03)
The oxidative polymerization of tris(thienylphenyl)amine derivatives was performed in acetonitrile by electrochemical and chemical methods. Oligomers were synthesized by stepwise coupling using coupling reactions. The polymer prepared using the trifunctio
