3401-29-4Relevant academic research and scientific papers
UNE VOIE D'ACCES RAPIDE ET PRATIQUE AU TETRAKIS(TRIMETHYLSILYL)-ALLENE ET AU BIS(TRIMETHYLSILYL)-1,3 PROPYNE
Bennetau, Bernard,Youhouvoulou N'Gabe, Denis,Dunogues, Jacques
, p. 3813 - 3816 (2007/10/02)
Complete silylation of hexachlorobenzene using the Me3SiCl/Li/THF reagent at 0oC quantitatively affords tetrakis(trimethylsilyl)allene.This last upon a double protodesilylation with F3CCOOH at 0o, leads to the quantitative formation of 1,3-bis(trimethylsilyl)propyne via the 1,3,3-tris(trimethylsilyl)propyne.
