34013-89-3Relevant articles and documents
Cs2CO3-Catalyzed Aerobic Oxidative Cross-Dehydrogenative Coupling of Thiols with Phosphonates and Arenes
Song, Song,Zhang, Yiqun,Yeerlan, Adeli,Zhu, Bencong,Liu, Jianzhong,Jiao, Ning
supporting information, p. 2487 - 2491 (2017/02/23)
An efficient Cs2CO3-catalyzed oxidative coupling of thiols with phosphonates and arenes that uses molecular oxygen as the oxidant is described. These reactions provide not only a novel alkali metal salt catalyzed aerobic oxidation, but also an efficient approach to thiophosphates and sulfenylarenes, which are ubiquitously found in pharmaceuticals and pesticides. The reaction proceeds under simple and mild reaction conditions, tolerates a wide range of functional groups, and is applicable to the late-stage synthesis and modification of bioactive molecules.
2-Chloro-2,4-dioxo-3-methyl-1,3,2-thiazaphospholidine. Comments on its phosphorylating properties
Modro, Agnes M.,Modro, Tomasz A.
, p. 2552 - 2554 (2007/10/02)
2-Alkoxy-2,4-dioxo-3-methyl-1,3,2-thiazaphospholidines undergo facile ring-opening reactions with chloride ion, and, in particular, with water.This reactivity may limit their value as first intermediates in the sequential synthesis of phosphoric diesters from the parent 2-chloro-2,4-dioxo-3-methyl-1,3,2-thiazaphospholidine.
