340741-75-5Relevant academic research and scientific papers
Star-Shaped Compounds Having 1,3,5-Triazine Cores
Meier, Herbert,Holst, Hans Christof,Oehlhof, Annette
, p. 4173 - 4180 (2007/10/03)
The 1,3,5-triazine derivatives 1-4 having styryl or higher oligo(phenylenevinylene) chains in the 2-, 4-, and 6-positions represent star-shaped push-pull compounds. Alkoxy or dimethylamino groups on the peripheral benzene rings, which act as electron donors, and the central 1,3,5-triazine ring, which acts as an electron acceptor, cause intramolecular charge transfer (ICT) to occur in the absorption S0→S 1. Protonation of the 1,3,5-triazine core enhances the effect, as demonstrated by a bathochromic shift; a secondary protonation on the dimethylamino groups, however, leads to the breakdown of the ICT. Thus, the yellow compound Id first becomes violet and then colorless upon the addition of trifluoroacetic acid. In neutral solution, the long-wavelength absorption of the series 1f, 2b, 3, and 4 converges to λ∞ = 427 nm (with an effective conjugation length nECL = 7). The absorption of the corresponding protonated compounds approaches λ∞ = 515 nm (nECL = 6). Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.
Methylium ions with OPV chains - New NIR dyes
Meier, Herbert,Kim, Soungkyoo
, p. 1163 - 1167 (2007/10/03)
Carbinols, which contain three OPV chains, were generated in convergent syntheses. The extension of the conjugation leads to a bathochromic effect that shifts the absorption from the UV into the visible region. The carbinol series has a convergence limit
