34085-99-9Relevant academic research and scientific papers
SYNTHESIS OF (Z)-PREDOMINANT α,β-UNSATURATED NITRILES FROM ENONE CYANOHYDRIN DIETHYL PHOSPHATES: APPLICATION TO THE SYNTHESIS OF (+/-)-NUCIFERAL, (+/-)-(E)-AND -(Z)-NUCIFEROL, AND (+/-)-MANICONE
Yoneda, Ryuji,Harusawa, Shinya,Kurihara, Takushi
, p. 3163 - 3168 (2007/10/02)
Enone cyanohydrin diethyl phosphates reaced regio- and stereo-selectively with a variety of organocopper reagents to give γ-coupling products, (Z)-predominant alk-2-enenitriles.The methodology was applied to the synthesis of (+/-)-nuciferal, (+/-)-(E)- an
