34089-16-2Relevant academic research and scientific papers
Unusually weak metal-hydrogen bonds in HV(CO)4(P-P) and their effectiveness as H? donors
Choi, Jongwook,Pulling, Mary E.,Smith, Deborah M.,Norton, Jack R.
, p. 4250 - 4252 (2008/09/20)
The V-H bonds in HV(CO)4(P-P) are unusually weak (55 to 58 kcal/mol). They transfer H? to styrene more rapidly than CpCr(CO)3H does and are effective stoichiometric reagents for the cyclization of appropriate 1,6-dienes. C
Dinitrosylvanadium Complexes: X, L = NCMe, THF, OCMe2; X = Cl, Br, I
Naeumann, Fritz,Rehder, Dieter
, p. 1647 - 1653 (2007/10/02)
The reaction between complexes 6-npn> (n = 2, pn = Ph2P(CH2)2PPh2; n = 3, pn = MeC(CH2PPh2)3) and 2 in THF, acetonitrile or acetone, L, yields the products cis-X and 3-m/s
