34098-73-2Relevant academic research and scientific papers
Palladium-catalyzed stereospecific carboalkoxylation of 1,2-difluoro-1- iodoalkenes and α,β-difluoro-β-iodostyrenes
Wesolowski, Craig A.,Burton, Donald J.
, p. 2243 - 2246 (1999)
(E)- and (Z)-1,2-Difluoro-1-iodoalkenes and (E)- and (Z)-α, β- difluoro-β-iodostyrenes give the corresponding esters in the presence of catalytic Cl2Pd(PPh3)2, alcohol, trialkylamine, and carbon monoxide (80- 180 psi) under mild conditions in excellent yields with retention of configuration.
Copper(II) mediated homo-coupling of 1,2-difluorovinylstannanes
Blumenthal, Eric J.,Burton, Donald J.
, p. 109 - 115 (1999)
The reaction of substituted 1,2-difluorovinylstannanes with anhydrous Cu(OAc)2 in dimethylformamide, under an oxygen atmosphere, at room temperature stereospecifically gives the corresponding symmetrical 1,3-dienes in good to excellent yields.
