34147-09-6

Basic information

• Product Name: 1,6:3,4-Dianhydro-β-DL-allo-hexopyranose
• CAS NO: 34147-09-6
• Molecular Weight: 144.127
• Mol File: 34147-09-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,6:3,4-Dianhydro-β-DL-allo-hexopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,6:3,4-Dianhydro-β-DL-allo-hexopyranose(34147-09-6)
• EPA Substance Registry System: 1,6:3,4-Dianhydro-β-DL-allo-hexopyranose(34147-09-6)

Safety Data

• Hazardous Substances Data: 34147-09-6(Hazardous Substances Data)

Upstream product

• 50705-28-7 1,6-anhydro-3,4-dideoxy-β-D-threo-hex-3-enopyranose 

Downstream Products

• 58394-32-4 1,6-anhydro-2,3-dideoxy-β-threo-hex-2-enopyranose 
• 33647-85-7 isolevoglucosenone 
• 58238-41-8 C₆H₆O₄ 
• 24707-42-4 4-deoxy-D-mannopyranoside 
• 155974-62-2 1,6-anhydro-4-deoxy-4-<(1S)-(1,4,6/5)-4,5,6-trihydroxy-3-hydroxymethylcyclohex-2-enylamino>-β-D-mannopyranose 
• 155874-50-3 1,6:3,4-dianhydro-2-thio-2-S-(p-tolyl)-β-D-galactopyranose 
• 6167-32-4 O²-(toluene-4-sulfonyl)-1,6;3,4-dianhydro-β-D-talopyranose 

Relevant articles and documents

A Domino Epoxide Ring-Opening Xanthate Migration Reaction: An Alternative Entry to Thiosugars

A sterereospecific and efficient synthesis of thiosugars derived from levoglucosenone and methyl α-d-glucopyranoside was developed by a domino epoxide ring opening- xanthate migration to afford 1,3-oxathiolane-2-thiones in high yields. The stereochemical outcome of the new C–S bond was defined by the configuration of the starting materials. The 1,3-oxathiolane-2-thiones were subsequently submitted to a second tandem reaction affording the corresponding 2,3-episulfide alcohols. The thiosugars obtained are useful building blocks for the synthesis of thiooligosaccharides with potential biological properties.