34158-75-3

Basic information

• Product Name: 4-IODOBENZALDEHYDE OXIME
• Synonyms: 4-IODOBENZALDEHYDE OXIME;4-IODOBENZALDOXIME;SYN-4-IODOBENZALDEHYDE OXIME
• CAS NO: 34158-75-3
• Molecular Formula: C₇H₆INO
• Molecular Weight: 247.03
• Product Categories: Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes
• Mol File: 34158-75-3.mol
• Article Data: 12

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-IODOBENZALDEHYDE OXIME(CAS DataBase Reference)
• NIST Chemistry Reference: 4-IODOBENZALDEHYDE OXIME(34158-75-3)
• EPA Substance Registry System: 4-IODOBENZALDEHYDE OXIME(34158-75-3)

Safety Data

• Hazardous Substances Data: 34158-75-3(Hazardous Substances Data)

Upstream product

• 87-91-2 diethyl (2R,3R)-tartrate 
• 18282-51-4 4-iodo-benzyl alcohol 
• 15164-44-0 p-(iodophenyl)carboxaldehyde 
• 3058-39-7 4-iodobenzonitrile 
• 555-16-8 4-nitrobenzaldehdye 

Downstream Products

• 3058-39-7 4-iodobenzonitrile 
• 1262439-32-6 N-((3-(4-iodophenyl)isoxazol-5-yl)methyl)-2-(diethylamino)ethanamide 
• 29305-61-1 N-hydroxy-4-iodobenzenecarboxyimidoyl chloride 

Relevant articles and documents

The local and natural sources in synthetic methods: the practical synthesis of aryl oximes from aryl aldehydes under catalyst-free conditions in mineral water

The synthesis of oximes from aryl aldehydes was prepared using hydroxylamine hydrochloride. The obtained oxime compounds were synthesized at maximum efficiency in mineral water at room temperature. The developed method is economical, practical and environmentally friendly. All of the aldehydes were converted the oxime a method using local sources and useful for industrial applications is introduced in the literature. Graphic abstract: In this study, addition elimination reaction, one of the important reactions of organic chemistry, was carried out using local sources. With this reaction, aryl oximes were obtained from aryl aldehydes in mineral water under catalyst-free conditions.[Figure not available: see fulltext.]

A Transition-Metal-Free One-Pot Cascade Process for Transformation of Primary Alcohols (RCH2OH) to Nitriles (RCN) Mediated by SO2F2

A new transition-metal-free one-pot cascade process for the direct conversion of alcohols to nitriles was developed without introducing an “additional carbon atom”. This protocol allows transformations of readily available, inexpensive, and abundant alcohols to highly valuable nitriles.

Synthesis of Nitriles from Aldoximes and Primary Amides Using XtalFluor-E

The dehydration reaction of aldoximes and amides for the synthesis of nitriles using [Et2NSF2]BF4 (XtalFluor-E) is described. Overall, the reaction proceeds rapidly (normally 1 h) at room temperature in an environmentally benign solvent (EtOAc) with only a slight excess of the dehydrating agent (1.1 equiv). A broad scope of nitriles can be prepared, including chiral nonracemic ones. In addition, in a number of cases, further purification of the nitrile after the workup was not required.