34159-03-0

Basic information

• Product Name: N-(4-CHLORO-2-FORMYLPHENYL)-4-METHYLBENZENESULFONAMIDE
• Synonyms: N-(4-CHLORO-2-FORMYLPHENYL)-4-METHYLBENZENESULFONAMIDE
• CAS NO: 34159-03-0
• Molecular Formula: C₁₄H₁₂ClNO₃S
• Molecular Weight: 0
• Mol File: 34159-03-0.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 463.7°C at 760 mmHg
• Flash Point: 234.3°C
• Appearance: /
• Density: 1.418g/cm³
• Vapor Pressure: 8.86E-09mmHg at 25°C
• Refractive Index: 1.636
• CAS DataBase Reference: N-(4-CHLORO-2-FORMYLPHENYL)-4-METHYLBENZENESULFONAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-CHLORO-2-FORMYLPHENYL)-4-METHYLBENZENESULFONAMIDE(34159-03-0)
• EPA Substance Registry System: N-(4-CHLORO-2-FORMYLPHENYL)-4-METHYLBENZENESULFONAMIDE(34159-03-0)

Safety Data

• Hazardous Substances Data: 34159-03-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H12ClNO3S/c1-10-2-5-13(6-3-10)20(18,19)16-14-7-4-12(15)8-11(14)9-17/h2-9,16H,1H3

Upstream product

• 6628-86-0 5-chloro-2-nitrobenzaldehyde 
• 73033-58-6 5-chloro-2-nitrobenzyl alcohol 
• 37585-25-4 2-amino-5-chlorobenzyl alcohol 
• 98-59-9 p-toluenesulfonyl chloride 
• 941-55-9 4-toluenesulfonyl azide 
• 587-04-2 m-Chlorobenzaldehyde 
• 635-21-2 5-chloroanthranilic acid 
• 675578-47-9 N-(4-chloro-2-(hydroxymethyl)phenyl)-4-methylbenzenesulfonamide 
• 247237-38-3 N-p-toluenesulfonyl-5-chloro-anthranilic acid methyl ester 
• 5202-89-1 4-chlorobenzenesulfonyl chloride 

Downstream Products

• 402822-77-9 N-allyl-N-p-toluenesulfonyl-4-chloro-2-ethenylaniline 
• 1613505-50-2 C₂₄H₁₈ClNO₃S 
• 1613505-72-8 C₁₇H₁₆ClNO₃S 
• 675578-48-0 N-allyl-N-p-toluenesulfonyl-4-chloro-2-formylaniline 

Relevant articles and documents

Intramolecular Umpolung Allylation of Imines

An intramolecular umpolung allylation of imines is reported. This reaction occurs via the intermediacy of 2-azaallyl anions. It could proceed either under transition-metal-catalyzed conditions or under transition-metal-free conditions. Importantly, this a

Diastereoselective Construction of Cyclopropane-Fused Tetrahydroquinolines via a Sequential [4 + 2]/[2 + 1] Annulation Reaction

A sequential [4 + 2]/[2 + 1] annulation of α-aryl vinylsulfoniums with 2-aminochalcones and 2-(2-aminobenzylidene)-1H-indene-1,3(2H)-dione is reported that affords a series of cyclopropane-fused tetrahydroquinolines. The salient features of this novel and practical transformation include high efficiency, transition-metal-free nature, operational simplicity, and outstanding functional group tolerance.

A nickel(ii)-catalyzed asymmetric intramolecular Alder-ene reaction of 1,7-dienes

A highly diastereo- and enantioselective intramolecular Alder-ene reaction with an alkene as the enophile has been developed by using a chiral N,N′-dioxide/nickel(ii) complex as the catalyst. This protocol provides a facile route towards the synthesis of diverse 3,4-disubstituted chroman, tetrahydroquinoline, piperidine and thiochroman derivatives in high yields with good to excellent diastereo- and enantioselectivities.