34164-52-8

Basic information

• Product Name: (2,2-dimethylpent-4-en-1-yl)magnesium bromide
• Synonyms: (2,2-dimethylpent-4-en-1-yl)magnesium bromide
• CAS NO: 34164-52-8
• Molecular Weight: 201.389
• Mol File: 34164-52-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2,2-dimethylpent-4-en-1-yl)magnesium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: (2,2-dimethylpent-4-en-1-yl)magnesium bromide(34164-52-8)
• EPA Substance Registry System: (2,2-dimethylpent-4-en-1-yl)magnesium bromide(34164-52-8)

Safety Data

• Hazardous Substances Data: 34164-52-8(Hazardous Substances Data)

Upstream product

• 76207-20-0 5-bromo-4,4-dimethylpent-1-ene 

Relevant articles and documents

gem-Dimethyl Effect in a Grignard Reagent Cyclization-Cleavage Rearrengament

(2,2-Dimethyl-4-penten-1-yl)magnesium bromide (1) is in equilibrium with its cyclic isomer, magnesium bromide (2).The equilibrium constant for this cyclization has a value of 2E-3.The gem-dimethyl substitution leads to an increase of a factor of about 22 in the equilibrium constant and also retards the rate of cleavage of 2.The sources of the gem-dimethyl effect in this system are discussed.