3419-46-3Relevant academic research and scientific papers
Organic Laser Molecule with High Mobility, High Photoluminescence Quantum Yield, and Deep-Blue Lasing Characteristics
De, Jianbo,Dong, Huanli,Fu, Hongbing,Gao, Haikuo,Hu, Wenping,Li, Shuai,Liao, Qing,Liu, Dan,Ma, Suqian,Ou, Qi,Peng, Qian,Qin, Zhengsheng,Shuai, Zhigang,Tian, Wenjing,Xu, Bin,Zhang, Xiaotao,Zhen, Yonggang
, p. 6332 - 6339 (2020)
Here, we design and synthesize an organic laser molecule, 2,7-diphenyl-9H-fluorene (LD-1), which has state-of-the-art integrated optoelectronic properties with a high mobility of 0.25 cm2 V-1 s-1, a high photoluminescence quantum yield of 60.3%, and superior deep-blue laser characteristics (low threshold of Pth = 71 μJ cm-2 and Pth = 53 μJ cm-2 and high quality factor (Q) of a?3100 and a?2700 at emission peaks of 390 and 410 nm, respectively). Organic light-emitting transistors based on LD-1 are for the first time demonstrated with obvious electroluminescent emission and gate tunable features. This work opens the door for a new class of organic semiconductor laser molecules and is critical for deep-blue optical and laser applications.
Fluorene derivative and preparation method and application thereof
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Paragraph 0117-0130, (2020/06/30)
The invention discloses a compound shown as a formula (I) and a preparation method thereof. The two R are the same or different; the two R1 are the same or different; each of R and R1 is independentlyselected from the group consisting of: unsubstituted or
Photochemical Degradation of Various Bridge-Substituted Fluorene-Based Materials
Kobin, Bj?rn,Behren, Sandra,Braun-Cula, Beatrice,Hecht, Stefan
, p. 5474 - 5480 (2016/07/30)
Photochemical degradation is an important issue to be overcome in advancing the lifetime of fluorene-containing conjugated polymers. In order to optimize the inertness of the materials, a quantitative measure for the efficiency of degradation is needed. Here, we introduce a method to measure a relative quantum yield of the photochemical degradation by monitoring the kinetics of the process by means of UV/vis spectroscopy and liquid chromatography (LC) techniques. This method is employed to a set of differently substituted 2,7-diphenylfluorenes, serving as model compounds for polyfluorene materials. Our measurements show that the quantum yield changes by orders of magnitude upon varying the bridge substituents and that altered kinetics indicate changing degradation mechanisms.
Selective and general exhaustive cross-coupling of di-chloroarenes with a deficit of nucleophiles mediated by a Pd-NHC complex
Groombridge, Benjamin J.,Goldup, Stephen M.,Larrosa, Igor
supporting information, p. 3832 - 3834 (2015/03/30)
We report the first example of a general, exhaustive Pd-mediated cross-coupling of polychloroarenes in the presence of a deficit of nucleophiles, mediated by the highly active PEPPSI-IPent catalyst. Our results indicate that this catalyst system may be applicable to the pseudo-living polymerisation of chloroarene monomers.
[Pd(Cl)2(P(NC5H10)(C6H 11)2)2] - A highly effective and extremely versatile palladium-based negishi catalyst that efficiently and reliably operates at low catalyst loadings
Bolliger, Jeanne L.,Frech, Christian M.
experimental part, p. 11072 - 11081 (2010/11/16)
[Pd(Cl)2(P(NC5H10)-(C6H 11)2]2] (1) has been prepared in quantitative yield by reacting commercially available [Pd(cod)(Cl)2] (cod = cyclooctadiene) with readily prepared 1-(dicyclohexylphosphanyl)piperidine in toluene under N2 within a few minutes at room temperature. Complex 1 has proved to be an excellent Negishi catalyst, capable of quantitatively coupling a wide variety of electronically activated, non-activated, deactivated, sterically hindered, heterocyclic, and functionalized aryl bromides with various (also heterocyclic) arylzinc reagents, typically within a few minutes at 100°C in the presence of just 0.01 mol% of catalyst. Aryl bromides containing nitro, nitrile, ether, ester, hydroxy, carbonyl, and carboxyl groups, as well as acetais, lactones, amides, anilines, alkenes, carboxylic acids, acetic acids, and pyridines and pyrimidines, have been successfully used as coupling partners. Furthermore, electronic and steric variations are tolerated in both reaction partners. Experimental observations strongly indicate that a molecular mechanism is operative.
The 1,3-diaminobenzene-derived aminophosphine palladium pincer complex {C6H3[NHP(piperidinyl)2]2Pd(Cl)} - A highly active Suzuki-Miyaura catalyst with excellent functional group tolerance
Bolliger, Jeanne L.,Frech, Christian M.
experimental part, p. 1075 - 1080 (2010/06/17)
The rapidly prepared 1,3-diaminobenzenederived aminophosphine pincer complex {C6H3 [NHP(piperidinyl)2] 2Pd(Cl)} (1) is an effective Suzuki catalyst with excellent functional group tolerance. Side-product formations, such as homocoupling, debromation or protodeboration have only rarely been detected and if so, were in all cases below the 5% level. The presented reaction protocol is universally applicable. Experimental observations indicate that palladium nanoparticles are the catalytically active form of 1.
Dichloro-bis(aminophosphine) complexes of palladium: Highly convenient, reliable and extremely active suzuki-miyaura catalysts with excellent functional group tolerance
Bolliger, Jeanne L.,Frech, Christian M.
supporting information; experimental part, p. 4075 - 4081 (2010/08/05)
Dichloro-bis(aminophosphine) complexes are stable depot forms of palladium nanoparticles and have proved to be excellent SuzukiMiyaura catalysts. Simple modifications of the ligand (and/or the addition of water to the reaction mixture) have allowed their formation to be controlled. Dichlorobis[1- (dicyclohexylphosphany1)piperidine]palladium (3), the most active catalyst of the investigated systems, is a highly convenient, reliable, and extremely active Suzuki catalyst with excellent functional group tolerance that enables the quantitative coupling of a wide variety of activated, nonactivated, and deactivated and/or sterically hindered functionalized and heterocyclic aryl and benzyl bromides with only a slight excess (1.1-1.2 equiv) of arylboronic acid at 80°C in the presence of 0.2 mol % of the catalyst in technical grade toluene in flasks open to the air. Conversions of >95% were generally achieved within only a few minutes. The reaction protocol presented herein is universally applicable. Side-products have only rarely been detected. The catalytic activities of the aminophosphine-based systems were found to be dramatically improved compared with their phosphine analogue as a result of significantly faster palladium nanoparticle formation. The decomposition products of the catalysts are dicyclohexylphosphinate, cyclohexylphosphonate, and phosphate, which can easily be separated from the coupling products, a great advantage when compared with non-water-soluble phosphine-based systems.
