342378-40-9Relevant academic research and scientific papers
Synthesis and properties of Schiff's bases derived from 1,3,4-thiadiazole as a mesogenic unit
Xu,Lu,Tai
, p. 151 - 159 (2007/10/03)
Some new liquid crystalline 2,5-disubstituted 1,3,4-thiadiazole derivatives incorporating a central group (-CH=N-) have been synthesized by treating 2-amino-5-(4-alkoxyphenyl)-1,3,4-thiadiazole with corresponding p-alkoxybenzaldehyde. Their structures have been characterized with Elementary Analysis, IR, 1HNMR and MS, and their properties were determined by using DSC and Texture. All 12 compounds are enantiotropic liquid crystals, and most of them exhibit nematic mesomorphism and broad smectic C mesomorphic ranges. Several compounds show only the smectic C mesophase. By introducing an -OH group into the phenyl ring the thermal stability of the mesophases increases due to the formation of a hydrogen bond.
