3424-15-5Relevant academic research and scientific papers
Cross-conjugated compounds: microwave spectrum and ring planarity of 3-methylene-1,4-cyclohexadiene
Hutter, Wolfgang,Bodenseh, Hans-Karl,Koch, Andreas
, p. 73 - 84 (2007/10/02)
The unstable 3-methylene-1,4-cyclohexadiene, an isomer of toluene, has been prepared from benzoic acid.The hydrocarbon can be handled quite easily in the solid state, and in the gas phase at low pressures.Rotational transitions have been measured from 12
Bimolecular Reactions of 3-Methylene-1,4-cyclohexadiene (p-Isotoluene), 5-Methylene-1,3-cyclohexadiene (o-Isotoluene), 1-Methylene-1,4-dihydronaphthalene (Benzo-p-isotoluene), and 9-Methylene-9,10-dihydroanthracene (Dibenzo-p-isotoluene)
Gajewski, Joseph J.,Gortva, Andrea M.
, p. 373 - 378 (2007/10/02)
3-Methylene-1,4-cyclohexadiene, 1, 5-methylene-1,3-cyclohexadiene, 2, 1-methylene-1,4-dihydronaphthalene, 5, and 9-methylene-9,10-dihydroanthracene, 8, react with second-order kinetics in benzene solution.The activation parameters for the reaction of 1,5,and 8, especially the frequency factor, suggest a nonconcerted reaction with little orientational demand in the transition state.The frequency factor for the reaction of 2 suggests a concerted pathway.The product distribution from each compound reinforces the kinetic observations.The products from the pyrolysisof 1 could be rationalized by a radical cage intermediate, which could combine or disproportionate.The reaction products from 5 indicate a radical chain oligomerization.The reaction of 8 gives an insoluble solid. o-Isotoluene (2) gives ene dimers.
